Go to Apps > Advanced app settings > App execution alieases and turn the python.exe, python3.exe off.

Author: o_oyao

Link: http://dyingdown.github.io/2023/12/26/Preventing-Command-Line-Python-from-Redirecting-to-Microsoft-Store-A-Quick-Fix/

License: All articles in this blog are licensed under CC BY-NC-SA 4.0 unless stating additionally.